Electron Structure
Electrons are negatively charged particles that move around the nucleus in fixed energy levels, also known as shells. The way these electrons are arranged is called the atom’s electronic configuration or electron structure.
Electron shells
Electrons occupy the lowest available energy levels (the ones closest to the nucleus) first.
Each shell has a maximum number of electrons it can hold:
Shell | Maximum electrons |
1 | 2 |
2 | 8 |
3 | 8 (for GCSE) |
💡 Always fill the shells in order: 1st shell → 2nd shell → 3rd shell
Electronic configuration
We can represent electron structure using numbers separated by dots or commas. These show how many electrons are in each shell.
Examples:
Element | Atomic number | Electron structure |
Hydrogen | 1 | 1 |
Helium | 2 | 2 |
Lithium | 3 | 2,1 |
Oxygen | 8 | 2,6 |
Neon | 10 | 2,8 |
Sodium | 11 | 2,8,1 |
The atomic number tells you the number of electrons, as atoms are neutral (electrons = protons).
Drawing electron shells
To draw an atom:
- Write the atomic number to find the number of electrons
- Use a nucleus circle in the middle
- Draw shells as circles around the nucleus
- Add electrons as dots or crosses in the shells
Link to the periodic table
- The period number = number of electron shells
- The group number (in Group 1–7) = number of electrons in the outer shell
Example:
- Sodium is in Group 1, Period 3
- It has 3 shells
- It has 1 electron in the outer shell
This helps explain reactivity and chemical behaviour, as elements in the same group have similar outer shell structures.
Questions
- How many electrons can the first shell hold?
- What does the atomic number tell you?
- What is the electron structure of oxygen?
- How does the group number relate to electron structure?
- Why do elements in the same group react similarly?
Summary
- Electrons are arranged in shells: 2, 8, 8…
- The number of electrons equals the number of protons in a neutral atom.
- Electron structures can be shown as numbers (e.g. 2,8,1 for sodium).
- Periods show the number of shells; groups show outer electrons.
- Electron arrangement determines reactivity and bonding.