Redox Reactions
A redox reaction is a reaction where one substance is reduced and another is oxidised. The word redox comes from reduction and oxidation happening at the same time.
What is oxidation and reduction?
There are two ways to define redox reactions:
1. In terms of oxygen:
- Oxidation = gain of oxygen
- Reduction = loss of oxygen
Example:
- Magnesium + oxygen → magnesium oxide
- Mg is oxidised (gains oxygen)
2. In terms of electrons:
- Oxidation = loss of electrons
- Reduction = gain of electrons
💡 Use the acronym OIL RIG: Oxidation Is Loss, Reduction Is Gain
Identifying redox reactions
In a redox reaction:
- One substance loses electrons → it is oxidised
- One substance gains electrons → it is reduced
You can spot redox reactions when:
- A metal reacts with oxygen
- A metal displaces another
- Electrons are transferred
Examples of redox reactions
Example 1: Magnesium + oxygen
2Mg + O₂ → 2MgO
- Mg is oxidised (gains oxygen)
- O₂ is reduced (forms oxide)
Example 2: Iron + copper sulfate
Fe + CuSO₄ → FeSO₄ + Cu
- Iron is oxidised (loses electrons to form Fe²⁺)
- Copper ions are reduced (gain electrons to become copper metal)
This is a displacement reaction and also a redox reaction.
Redox in terms of ions
Before | After | What happens |
Fe → Fe²⁺ + 2e⁻ | (oxidation) | Loses electrons |
Cu²⁺ + 2e⁻ → Cu | (reduction) | Gains electrons |
Questions
- What does redox stand for?
- What is oxidation in terms of electrons?
- What is the acronym for remembering redox?
- In Fe + CuSO₄, which element is reduced?
- What happens when a substance is oxidised?
Summary
- Redox reactions involve oxidation and reduction happening together
- Oxidation = gain of oxygen or loss of electrons
- Reduction = loss of oxygen or gain of electrons
- Use OIL RIG to remember the definitions
- Many displacement reactions are redox reactions
