Reversible Reactions
Most chemical reactions go one way, but some can go in both directions. These are called reversible reactions. The products can react to form the original reactants again.
What is a reversible reaction?
- A reversible reaction is one where the products can turn back into the reactants
- It is shown with a double arrow:
A + B ⇌ C + D - The forward reaction goes from left to right
- The backward reaction goes from right to left
Examples of reversible reactions
1. Hydrated copper(II) sulfate ⇌ anhydrous copper(II) sulfate + water
- Heating blue hydrated copper sulfate removes water and turns it white
- Adding water reverses the reaction and turns it blue again
2. Ammonium chloride ⇌ ammonia + hydrogen chloride
- On heating, ammonium chloride breaks into gases
- When cooled, the gases recombine
Energy in reversible reactions
- If the forward reaction is exothermic, the reverse is endothermic, and vice versa
- The amount of energy transferred is the same in both directions
💡 Exothermic one way = endothermic the other
Closed system
- A closed system means no reactants or products can escape
- Reversible reactions in a closed system can reach equilibrium
Equilibrium is covered in the next lesson.
Questions
- What does the symbol ⇌ mean?
- What type of reaction can go both ways?
- If the forward reaction is endothermic, what is the reverse reaction?
- What happens in a closed system?
- Give one example of a reversible reaction.
Summary
- Reversible reactions go in both directions
- Shown with the symbol ⇌
- The products can react to reform the reactants
- Energy changes are opposite in each direction
- In a closed system, the reaction can reach equilibrium
